Structure-reactivity correlation for the ligand-decelerated catalytic osmium tetraoxide dihydroxylation of alkenes

Erdik E., KAHYA N. D.

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, cilt.15, sa.4, ss.229-232, 2002 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 15 Sayı: 4
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1002/poc.475
  • Dergi Adı: JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.229-232
  • Anahtar Kelimeler: ligand-decelerated catalysis, osmium tetraoxide dihydroxylation, V-shaped Hammett plot, ASYMMETRIC DIHYDROXYLATION, HIGH ENANTIOSELECTIVITY, KINETIC ROLE, OLEFINS, HYDROXYLATION, OXIDATIONS
  • Ankara Üniversitesi Adresli: Evet

Özet

Kinetic studies on the ligand-decelerated catalytic OsO4 dihydroxylation of seven substituted styrenes with trimethylamine-N-oxide in the absence and in the presence of pyridine ligand have been carried out. The rates correlate with the Hammett relationship and V-shaped plots with a maximum are in agreement with the oxidation of osmate(VI) ester in the rate-determining step. Copyright (C) 2002 John Wiley Sons, Ltd.