The preparation and characterization of conductive poly(ethylene terephthalate)/polyaniline composite fibers using benzoyl peroxide

Cetin E., KARAKIŞLA M., SAÇAK M.

FIBERS AND POLYMERS, cilt.9, sa.3, ss.255-262, 2008 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 9 Sayı: 3
  • Basım Tarihi: 2008
  • Doi Numarası: 10.1007/s12221-008-0040-2
  • Dergi Adı: FIBERS AND POLYMERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.255-262
  • Anahtar Kelimeler: poly(ethylene terephthalate) fiber, conductive fiber, polyaniline, conductive composite, benzoyl peroxide, INITIATED GRAFT-COPOLYMERIZATION, POLY(ETHYLENE-TEREPHTHALATE) FIBERS, OXIDATIVE POLYMERIZATION, PHYSICAL-PROPERTIES, POLYANILINE, FABRICS, POLYPYRROLE, TEXTILES, ANILINE, ACID
  • Ankara Üniversitesi Adresli: Evet

Özet

Conductive polyaniline (PAn)/poly(ethylene terephthalate) (PET) composite fibers were prepared by chemical polymerization of aniline in the presence of PET fibers using benzoyl peroxide (BZ(2)O(2)) in organic solvent/aqueous hydrochloric acid mixtures. The effects of polymerization conditions such as organic solvent/water ratio, oxidant, aniline and hydrochloric acid concentrations and temperature were investigated on the amount of PAn deposited on PET fiber and the electrical surface resistance of composite fibers. The maximum PAn content and the lowest electrical surface resistance of composite fibers were observed at HCl concentrations of 0.5 mol L-1. The properties of PAn/PET composite fibers such as density, diameter, tensile strength and breaking elongation were also investigated in comparison with those of pure PET. Characterization of conductive composite fibers was carried out by FTIR, TGA, SEM techniques, surface resistance measurements, and cross section images taken by optical microscope.