Bis[mu-N,N '-bis(salicylidene)-1,3-propanediaminecopper(II)]diiodolead(II)

Sari M., Durmus S., Atakol O., Svoboda I., Fuess H.

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, vol.57, 2001 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 57
  • Publication Date: 2001
  • Doi Number: 10.1107/s1600536801006511
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Directory of Open Access Journals, Civil Engineering Abstracts
  • Ankara University Affiliated: No

Abstract

In the title compound, bis[mu -N,N'-bis(salicylidene)-1,3-propanediamine]-1 kappa 4N,N',O,O':3 kappa O-2,O';2 kappa (4) N,N',O,O':3 kappa O-2,O'-diiodo-3 kappa I-2-dicopper(II)lead(II), [{Cu(C17H16N2O2)}(2)PbI2], the Pb atom is in a distorted octahedral environment coordinated by four O and two I atoms. The phenolic O atoms of the two organic ligands coordinate both Cu and Pb atoms, forming a bridge. The Pb-I bond distances are 3.0945 (9) and 3.1831 (9) Angstrom, and the Pb-O bond distances range from 2.492 (6) to 2.616 (6) Angstrom. The Pb . . . Cu bridging distances are 3.6331 (14) and 3.5662 (13) Angstrom.