The supercapacitor performance of hierarchical porous activated carbon electrodes synthesised from demineralised (waste) cumin plant by microwave pretreatment

GÜRTEN İNAL İ. I., Holmes S. M., YAĞMUR E., Ermumcu N., Banford A., AKTAŞ Z.

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, vol.61, pp.124-132, 2018 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 61
  • Publication Date: 2018
  • Doi Number: 10.1016/j.jiec.2017.12.009
  • Journal Name: JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.124-132
  • Keywords: Biomass, Acid washing, Microwave pretreatment, Activated carbon electrode, Supercapacitor, DOUBLE-LAYER CAPACITORS, CHEMICAL ACTIVATION, KOH-ACTIVATION, ELECTROCHEMICAL CAPACITORS, THERMAL-DEGRADATION, MESOPOROUS CARBONS, NANOPOROUS CARBON, PHOSPHORIC-ACID, METHYLENE-BLUE, MINERAL MATTER
  • Ankara University Affiliated: Yes

Abstract

Activated carbon (AC) was prepared from waste cumin utilising the chemical activation method. The cumin was separately washed with HCI and HF to remove minerals. The surface areas of AC of the acid washed samples (AC-HCl, AC-HF) were 1468 and 1472 m(2)/g, compared with 1361 m(2)/g for AC obtained directly from the precursor. Washing with the acids improved the supercapacitor performance through a significant decrease in the internal resistance of electrodes. The specific capacitances of electrodes using ACs prepared from acid washed samples (HCl and HF) were 127F/g and 155F/g at current density of 1.5 mA/cm(2), compared with 117 F/g from the unwashed precursor. Crown Copyright (C) 2017 Published by Elsevier B.V. on behalf of The Korean Society of Industrial and Engineering Chemistry. All rights reserved.