Protonation constants of some N-substituted amidoximes in a 50% ethanol-water mixture (v/v)


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Durust N., Akay M. A., Durust Y., Kilic E.

ANALYTICAL SCIENCES, cilt.16, sa.8, ss.825-827, 2000 (SCI-Expanded, Scopus) identifier identifier

Özet

The stoichiometric protonation constants of some N-substituted amidoximes have been determined potentiometrically in a 50% ethanol-water mixture (v/v) at 25 degrees C and at constant ionic strength. A calculation was performed using a PC software. The variation of the protonation constants of these compounds was interpreted on the basis of structural effects exposed by the substituents and main skeleton.