Synthesis of a new system containing a pyramidalized double bond:: Lack of reactivity of a strongly protected pyramidalized double bond

SARAÇOĞLU N., Balci M.

HELVETICA CHIMICA ACTA, cilt.84, sa.3, ss.707-714, 2001 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 84 Sayı: 3
  • Basım Tarihi: 2001
  • Dergi Adı: HELVETICA CHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Sayfa Sayıları: ss.707-714
  • Ankara Üniversitesi Adresli: Hayır

Özet

The chemical reactivity of syn-3 was investigated. The experimental results showed that the central double bond of this system is inert toward chemical reactions. To determine the reactivity of this central double bond. we synthesized syn- and anti-7 and recorded their photoelectron spectra. Low first-ionization potentials of syn- and anti-7 (7.6 eV) dearly indicated that these compounds should be highly reactive.