The crystal structure of a N-(2-thiophenyl)-salicylaldiminopiperidino nickel(II) complex

KABAK M., ELERMAN Y., OZBEY S., ATAKOL O.

Journal of Chemical Crystallography, vol.25, no.5, pp.259-262, 1995 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 25 Issue: 5
  • Publication Date: 1995
  • Doi Number: 10.1007/bf01665180
  • Journal Name: Journal of Chemical Crystallography
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.259-262
  • Keywords: SCHIFF BASE, PIPERIDINE, SALICYLALDIMINE
  • Ankara University Affiliated: Yes

Abstract

The crystal and molecular structure of the title complex, C18H19N2OSNi, has been determined by direct methods. The compound crystallizes in monoclinic crystal system with a=11.968(1), b=12.182(1), c=12.399(1) Å, β=115.23(1)°, space group P21/n. Nickel is in a slightly distorted square-planar environment of two nitrogens [1.881(2) and 1.952(2) Å] and one oxygen [1.856(3) Å] and one sulphur [2.138(2) Å] atom. Ni is 0.005 Å out of the plane of its ligands. © 1995 Plenum Publishing Corporation.