{4-methyl-2-[(2-oxidobenzylidene)amino]-phenolato(2-)-N,O,O′} (piperidine-N)-nickel(II)


Atakol O., KENAR A., Ercan F., Sari M., Yagbasan R.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.52, sa.8, ss.1881-1884, 1996 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 52 Sayı: 8
  • Basım Tarihi: 1996
  • Doi Numarası: 10.1107/s0108270196003484
  • Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
  • Sayfa Sayıları: ss.1881-1884
  • Ankara Üniversitesi Adresli: Evet

Özet

In the title compound, [Ni(C14H11NO2)(C5H11N)], the coordination geometry at the Ni atom was found to be a slightly distorted square-planar polygon formed by the O, N and O′ donor atoms of the tridentate ligand and the N donor atom of the monodentate ligand [O-Ni-N 86.6 (2)-95.9 (3)°, Ni-O 1.810 (5) and 1.833 (4), Ni-N 1.862 (6) and 1.933 (7) Å]. The diamagnetic properties of the complex, determined by the Gouy method, are in agreement with the planar coordination.