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Heteroatom Chemistry, vol.25, no.2, pp.83-94, 2014 (SCI-Expanded)
The condensation reactions of tetrachloro mono (1 and 2) and bisferrocenyl spirocyclotriphosphazenes (3-5) with morpholine in tetrahydrofuran gave the partly morpholino-substituted ferrocenylphosphazenes. When the reactions were carried out with equal amounts of 1-5 and morpholine, the mono-substituted ferrocenylphosphazenes (1a, 3a-5a) formed as the major product. While the reactions were made with 1 equiv of 1-5 and 2 equiv of morpholine, the corresponding geminal-phosphazenes (1b-5b) were isolated. In addition, the condensation reactions of 1 equiv of 1-5 and 3 equiv of morpholine resulted in the formation of di-(1b-5b), tri-(2c-5c), and tetra-substituted phosphazenes. The tri-substituted compounds were isolated as major products. Some new phosphazenes have stereogenic P center(s). The stereogenic properties of 1a and 2c were investigated using 31P nuclear magnetic resonance (NMR) spectroscopy in the presence of the chiral solvating agent; (S)-(+)-2,2,2- trifluoro-1-(9′-anthryl)ethanol. The structures of all the phosphazenes were characterized by one-dimensional 1H, 13C, and 31P NMR, and two-dimensional heteronuclear single quantum coherence spectral data. The salient spectral properties of the phosphazenes were presented. © 2014 Wiley Periodicals, Inc.