The effect of electrochemically formed aluminum salts on the electrochemical cyclisation of methyl cinnamate

GÜLLÜ M.

TETRAHEDRON LETTERS, cilt.40, sa.16, ss.3225-3228, 1999 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 40 Sayı: 16
  • Basım Tarihi: 1999
  • Doi Numarası: 10.1016/s0040-4039(99)00369-x
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.3225-3228
  • Anahtar Kelimeler: electrochemical reactions, cyclisation, sacrificial anode, ONE-STEP SYNTHESIS, ELECTROREDUCTIVE CYCLIZATION, CYCLIC-COMPOUNDS, REDUCTION, ESTERS
  • Ankara Üniversitesi Adresli: Evet

Özet

Electrochemical cyclisation of methyl cinnamate with dielectrophiles has been improved by the presence of an aluminum salt which was pre-formed in situ by the electrolysis of a carboxylic acid with a sacrificial aluminum anode. High yields of three, five and six-membered cyclic products have been obtained in the reactions of methyl cinnamate with dichloromethane, 1,3-dibromopropane, and 1,4-dibromobutane. (C) 1999 Elsevier Science Ltd. AU. rights reserved.