Synthesis, characterization and optical limiting properties of novel ball-type four tert-butylcalix[4]arene bridged double-decker lutetium(III) and indium(III) phthalocyanines

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Ceyhan T., YAĞLIOĞLU H. G., ÜNVER H., SALİH B., Erbil M. K., ELMALI A., ...Daha Fazla

Macroheterocycles, cilt.1, sa.1, ss.44-49, 2008 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 1 Sayı: 1
  • Basım Tarihi: 2008
  • Doi Numarası: 10.6060/mhc2008.1.44
  • Dergi Adı: Macroheterocycles
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.44-49
  • Ankara Üniversitesi Adresli: Evet

Özet

Novel ball type four tert-butylcalix[4]arene bridged double-decker lutetium(III) phthalocyanine [LuPc2(tbca)4] 2 which exhibit nonlinear optical limiting behaviour and indium(III) phthalocyanine [InPc2(tbca)4] 3 were prepared by the reaction of 1,3-bis(3,4-dicyanophenoxy)-4-tert-butylcalix[4]arene 1 and the corresponding metal salts (Lu(OAc)3·3H2O and InCl3) in the presence of lithium metal in 1-pentanol. Newly synthesized phthalocyanines were characterized by elemental analysis, UV-vis, IR, MALDI-TOF MS and 1H NMR spectra. © ISUCT Publishing.