THE CHEMISTRY OF 1H-CYCLOPROPA[B]NAPHTHALENE

DURUCASU I., SARAÇOĞLU N., BALCI M.

TETRAHEDRON LETTERS, cilt.32, sa.48, ss.7097-7098, 1991 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 32 Sayı: 48
  • Basım Tarihi: 1991
  • Doi Numarası: 10.1016/0040-4039(91)85050-f
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.7097-7098
  • Ankara Üniversitesi Adresli: Hayır

Özet

1H-cyclopropa[b]naphthalene reacts with PTAD, tetracyanoethylene (TCNE) and benzyne to afford insertion-products 3, 4, and 5. Cheletropic addition of dichlorocarbene to 2 provides cyclobutanaphthalene 6. Hydrolysis and reductive elimination of 6 result in the formation of 7 and 8.