{[μ-N,N′-Bis(salicylidene)-1,3-propanediaminato]copper(II)} dichloromercury(II)

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Atıf İçin Kopyala

Atakol O., Arici C., Tahir M., KENAR A., Ulku D.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.55, sa.9, ss.1416-1418, 1999 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 55 Sayı: 9
• Basım Tarihi: 1999
• Doi Numarası: 10.1107/s0108270199007076
• Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.1416-1418
• Ankara Üniversitesi Adresli: Evet

Özet

The title compound, [CuHgCl2(C17H16N2O2)], is a hetero-dinuclear complex containing CuII and HgII ions. The CuII centre has a distorted square-planar coordination involving two O and two N atoms from the imine-phenol ligand, with Cu - O distances of 1.920 (3) and 1.926 (2) Å, and Cu - N distances of 1.966 (3) and 1.986 (4) Å. The coordination around the HgII centre consists of two chloride ions at distances of 2.343 (1) and 2.325 (2) Å, and two phenolic O atoms of the organic ligand at distances of 2.516 (2) and 2.421 (3) Å. The Cu⋯Hg separation is 3.5301 (8) Å.