Triterpene saponins from Cyclamen coum var. coum

Çaliş I., Yürüker A., Tanker N., Wright A. D., Sticher O.

Planta Medica, cilt.63, sa.2, ss.166-170, 1997 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 63 Sayı: 2
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1055/s-2006-957637
  • Dergi Adı: Planta Medica
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.166-170
  • Anahtar Kelimeler: cyclacoumin, Cyclamen coum, cyclaminorin, mirabilin lactone, Primulaceae, saponins
  • Ankara Üniversitesi Adresli: Evet

Özet

From the tubers of Cyclamen coum (Primulaceae) three new saponins, cyclaminorin (1), cyclacoumin (3) and mirabilin lactone (4) were isolated together with a known saponin, deglucocyclamin (2). The structures of the new compounds were established as 13β,28-epoxy-3β-{{[β-D-glucopyranosyl-(1→2)][β-D-glucopyranosyl -(1→4)]-α-L-arabinopyranosyl{oxy{16α-hydroxy-olean-30-al (1), 13β,28-epoxy-3β-{{[β-D-xylopyranosyl(1→2)-β-D-glucopyranosyl-(1 →4)]-[β-D-glucopyranosyl-(1→2)]α-L-arabinopyranosyl{oxy{-16α,23 -dihydroxy-olean-30-al (3) and 16α-hydroxy-3β-{{{[β-D-xylopyranosyl-(1→2)]-[β-D-glucopyranosy l-1→6)]-β-D-glucopyranosyl-(1→4){-[β-D-glucopyranosyl(1→2)]-α-L -arabinopyranosyl{-oxy{olean-12-eno-30,28-lactone (4). Structure elucidations were accomplished using both spectral (NMR, MS, IR) and chemical methods.