Light-sensitive monolayer-thick nanocrystal skins of face-down self-oriented colloidal quantum wells

Bozkaya T., IŞIK F., Bozkaya I., Delikanli S., Unal E., Demir H. V.

NANOSCALE, cilt.15, sa.43, ss.17583-17588, 2023 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 15 Sayı: 43
  • Basım Tarihi: 2023
  • Doi Numarası: 10.1039/d3nr04065h
  • Dergi Adı: NANOSCALE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Biotechnology Research Abstracts, Chemical Abstracts Core, Chimica, Compendex, INSPEC, MEDLINE, Metadex
  • Sayfa Sayıları: ss.17583-17588
  • Ankara Üniversitesi Adresli: Hayır

Özet

Colloidal quantum wells (CQWs), a quasi-two-dimensional, atomically-flat sub-family of semiconductor nanocrystals, are well suited to produce excellent devices for photosensing applications thanks to their extraordinarily large absorption cross-sections. In this work, we propose and demonstrate a new class of light-sensitive nanocrystal skins (LS-NS) that employ a monolayer of face-down orientation-controlled self-assembled CQWs as the active absorbing layer in the UV-visible range. This CQW LS-NS platform enables non-conventional photosensing operation that relies on the strong optical absorption of the monolayered assembly of CQWs and the subsequent photogenerated potential build-up across the device, allowing for self-powered operation. Here such self-oriented CQWs reduce the surface roughness in their monolayer-thick film, essential to high device performance. Owing to their ease of fabrication and low cost, these devices hold great promise for large-scale use in semi-transparent photosensing surfaces. A new class of light-sensitive nanocrystal skins (LS-NS) that employ a monolayer of face-down orientation-controlled self-assembled CQWs as the active absorbing layer in the UV-visible range is developed.