The chemical synthesis of conductive polyaniline by using benzoyl peroxide

Karakisla M., Sacak M.

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY, cilt.A39, sa.11, ss.1349-1359, 2002 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: A39 Sayı: 11
  • Basım Tarihi: 2002
  • Doi Numarası: 10.1081/ma-120015735
  • Dergi Adı: JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1349-1359
  • Anahtar Kelimeler: benzoyl peroxide, chemical polymerization, polyanilme, INITIATED GRAFT-COPOLYMERIZATION, ACID-DOPED POLYANILINE, POLY(ETHYLENE-TEREPHTHALATE) FIBERS, OXIDATIVE POLYMERIZATION, ANILINE, FILMS
  • Ankara Üniversitesi Adresli: Evet

Özet

The chemical polymerization of aniline was carried out in acetonitrile/ water media by the use of benzoyl peroxide as an initiator. Among the acids chosen as dopant the highest yield was obtained in HCl with 24.8% and the highest conductance was observed in H2SO4 with 0.082 S cm(-1). The effect of HCl, benzoyl peroxide and aniline concentrations upon polyaniline yield and conductivity was also investigated. The polyaniline was characterized by conductivity measurements, UV-Vis and FTIR.