[N,N′-bis(salicylidene)-2,2-dimethyl-1,3-propanediaminato]nickel(II) and [N,N′-bis(salicylidene)-2,2-dimethyl-1,3-propanediaminato]copper(II)

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Atıf İçin Kopyala

Arici C., Ercan F., Kurtaran R., Atakol O.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.57, sa.7, ss.812-814, 2001 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 57 Sayı: 7
• Basım Tarihi: 2001
• Doi Numarası: 10.1107/s0108270101008150
• Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.812-814
• Ankara Üniversitesi Adresli: Evet

Özet

In the title compounds, (2,2′-[2,2-dimethyl-1,3-propanediyl-bis(nitrilomethylidyne)] diphenolato-κ4 N, N′,O,O′) nickel(II), [Ni(C19H20N2O2)], and (2,2′-[2,2-dimethyl-1,3-propanediyl-bis(nitrilomethylidyne)] diphenolato-κ4N,N′,O,O′)copper(II), [Cu(C19H20N2O2)], the NiII and CuII atoms are coordinated by two iminic N and two phenolic O atoms of the N,N′-bis(salicylidene)-2,2-dimethyl-1,3-propanediaminate (SALPD2-, C17H16- N2O22-) ligand. The geometry of the coordination sphere is planar in the case of the NiII complex and distorted towards tetrahedral for the CuII complex. Both complexes have a cis configuration imposed by the chelate ligand. The dihedral angles between the N/Ni/O and N/Cu/O coordination planes are 17.20 (6) and 35.13 (7 )°, respectively.