X-ray structure of {[μ-N,N′-Bis(salicylidene)-1,3-propane-diamine] (dimethylformamide) zinc(II)} dibromo cadmium(II)

Arici C., Ulku D., Aksu M., Atakol O.

Journal of Chemical Crystallography, cilt.33, sa.11, ss.825-829, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 33 Sayı: 11
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1023/a:1027497427264
  • Dergi Adı: Journal of Chemical Crystallography
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.825-829
  • Anahtar Kelimeler: crystal structure, dinuclear zinc and cadmium complex, MAGNETIC-PROPERTIES, CRYSTAL-STRUCTURE, COMPLEXES, COPPER(II), NUCLEARITY, LIGANDS
  • Ankara Üniversitesi Adresli: Evet

Özet

The title compound, forms crystals which are the orthorhombic system, space group P2 1 2 1 2 1 , with unit cell dimensions a = 10.3928(12) Å, b = 14.6298(13) Å, c = 15.9514(11) Å, V = 2425.3(4) Å 3 . The cell contains four molecules. The structure is a heteronuclear dimeric complex with Zn II and Cd II ions. The coordination around the Zn II ion is distorted square-pyramid and the Cd II ion is distorted tetrahedral coordination. The Zn⋯Cd distance is 3.3594(7) Å.