Electrochemical reduction of methyl cinnamate in the presence of 1,3-bis(4-methyl phenylsulphonyloxy)propane

GÜLLÜ M.

TURKISH JOURNAL OF CHEMISTRY, cilt.23, sa.4, ss.361-367, 1999 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 23 Sayı: 4
  • Basım Tarihi: 1999
  • Dergi Adı: TURKISH JOURNAL OF CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.361-367
  • Anahtar Kelimeler: methyl cinnamate, electrochemical reduction, cyclisation, CYCLIC-COMPOUNDS
  • Ankara Üniversitesi Adresli: Evet

Özet

Electrochemical reduction of methyl cinnamate in the presence of a dielectrophile, such as 1,3-bis(4-methyl phenylsulphonyloxy)propane gives two major products: trans- (+/-) methyl 2-phenylcyclopentane-carboxylate and trans- (+/-) methyl 2,3-diphenyl-5-oxo-cyclopentanecarboxylate. The ratio of products basically depends on the electrolysis conditions.