AN N,N'-BIS(SALICYLIDENE)-1,3-PROPANEDIAMINE-NICKEL COMPLEX
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.49, pp.1905-1906, 1993 (SCI-Expanded)
- Publication Type: Article / Article
- Volume: 49
- Publication Date: 1993
- Doi Number: 10.1107/s0108270193004615
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
- Page Numbers: pp.1905-1906
- Ankara University Affiliated: No
Abstract
In the crystal structure of this Ni-II complex with bis(salicylidene)-1,3-diaminopropane, aqua{2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato}- nickel(II), nickel is five-coordinate with a water molecule at the apex of a square pyramid. The complex has symmetry m and the two Schiff base moieties, which in themselves are planar, are inclined at 38.6 (4)degrees to each other, forming a shallow umbrella form. The configuration at the N atoms is planar, as would be expected of sp(2) hybridization.