AN N,N'-BIS(SALICYLIDENE)-1,3-PROPANEDIAMINE-NICKEL COMPLEX

ELERMAN, Y; KABAK, M; ATAKOL, O

doi:10.1107/s0108270193004615

AN N,N'-BIS(SALICYLIDENE)-1,3-PROPANEDIAMINE-NICKEL COMPLEX

ELERMAN Y., KABAK M., ATAKOL O.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, cilt.49, ss.1905-1906, 1993 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 49
Basım Tarihi: 1993
Doi Numarası: 10.1107/s0108270193004615
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
Sayfa Sayıları: ss.1905-1906
Ankara Üniversitesi Adresli: Hayır

Özet

In the crystal structure of this Ni-II complex with bis(salicylidene)-1,3-diaminopropane, aqua{2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato}- nickel(II), nickel is five-coordinate with a water molecule at the apex of a square pyramid. The complex has symmetry m and the two Schiff base moieties, which in themselves are planar, are inclined at 38.6 (4)degrees to each other, forming a shallow umbrella form. The configuration at the N atoms is planar, as would be expected of sp(2) hybridization.