1,3-Bis[2-(2-hydroxybenzylideneamino)phenoxy]propane


Hokelek T., Bilge S., Demiriz S., Ozguc B., Kilic Z.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.60, sa.11, 2004 (SCI-Expanded) identifier identifier identifier

Özet

The title compound {systematic name: 2,2′-[1,3-propanediyldioxydi-o- phenylenebis(nitrilomethylidyne)]diphenol}, C29-H26N 2O4, exists as the phenol-imine form in the crystal, and there are strong intramolecular O - H⋯N hydrogen bonds, with O⋯N distances of 2.545 (2) and 2.579 (2) Å. The C=N imine bond distances are in the range 1.276 (2)-1.279 (2) Å and the C=N - C bond angles are in the range 123.05 (16)-124.64 (17)°. The configurations about the C=N bonds are anti (1E).