{2-[(2-hydroxy-5-methylphenyl)imino-methyl]-4,6-dinitrophenolato(2-)-O,N , O′}-tris(3-methylpyridine-N)nickel(II)

Tahir, MN; Ulku, D; Atakol, ORHAN; Basgut, O

doi:10.1107/s0108270197016545

{2-[(2-hydroxy-5-methylphenyl)imino-methyl]-4,6-dinitrophenolato(2-)-O,N , O′}-tris(3-methylpyridine-N)nickel(II)

Atıf İçin Kopyala

Tahir M., Ulku D., Atakol O., Basgut O.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.54, sa.5, ss.623-625, 1998 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 54 Sayı: 5
Basım Tarihi: 1998
Doi Numarası: 10.1107/s0108270197016545
Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Sayfa Sayıları: ss.623-625
Ankara Üniversitesi Adresli: Evet

Özet

In the title compound, [Ni(C14H9N3O6)(C6H 7N)3], the coordination polyhedron around the NiII atom is a slightly distorted octahedron, with one N atom of the tridentate ligand and three N atoms of three monodentate ligands forming the equatorial plane. The apical positions are occupied by the two phenolic O atoms of the tridentate ligand. The Ni-O distances are 2.013 (2) and 2.008 (2) Å, and the Ni-N distances range from 2.043(2) to 2.168 (3) Å. The cis bond angles at NiII range from 82.75 (9) to 96.2(1)°. There are intramolecular, as well as intermolecular, hydrogen bonds in the structure.