Thermal decomposition of some linear trinuclear schiff base complexes with acetate bridges

Durmus S., Ergun U., Jaud J. C., EMREGÜL K. C., Fuess H., Atakol O.

Journal of Thermal Analysis and Calorimetry, cilt.86, sa.2, ss.337-346, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 86 Sayı: 2
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1007/s10973-005-7282-7
  • Dergi Adı: Journal of Thermal Analysis and Calorimetry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.337-346
  • Anahtar Kelimeler: DSC, TG-DTA, trinuclear Schiff base complex, CRYSTAL-STRUCTURE, ZINC-COMPLEXES, NICKEL(II), COBALT(II), BEHAVIOR, CO(II), COPPER
  • Ankara Üniversitesi Adresli: Evet

Özet

Ni(II)-M(II)-Ni(II) nuclear structured complexes were prepared from N,N'-bis(salicylidene)-1,3-propanediamine (LH2) and its derivatives N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-propanediamine (LDMH2) and N,N'-bis(salicylidene)-2-hydroxy-1,3-propanediamine (LOH3), where M represents one of the following metal ions; Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II). Two different μ-bridges are found between the metal nucleus of the complexes. The phenolic oxygens and acetate ions tend to form μ-bridges between the terminal Ni(II) ions and central metal(II) ion. The coordinatively bonded DMF molecules, in the complexes, were observed to abandon the structure between 160-180°C. Further heating resulted primarily in the thermal decomposition of the complexes above 310°C, whereas metal oxide residue mixtures were observed above 650°C. © 2006 Springer-Verlag.