PREPARATION AND CHARACTERIZATION OF NEW AMINO-SUBSTITUTED CROWNS AND PODANDS

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KILIC Z., WEBER E., GUNDUZ N., KILIC E., NAZIR H., HOKELEK T., ...Daha Fazla

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, cilt.47, sa.4, ss.547-552, 1992 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Sayı: 4
  • Basım Tarihi: 1992
  • Doi Numarası: 10.1515/znb-1992-0414
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.547-552
  • Anahtar Kelimeler: AMINO CROWNS, AMINO PODANDS, SYNTHESIS, SPECTROSCOPIC STUDIES, MACROCYCLIC POLYETHERS, ETHERS, COMPLEXATION
  • Ankara Üniversitesi Adresli: Evet

Özet

A number of macrocyclic (1b-3b) and linear oligoether compounds (4b-8b) with 2,2'-methylenebis(4-aminophenol) or 2-aminophenol characteristic building blocks have been synthesized by reduction of the corresponding nitro derivatives with Pd-C/hydrazine hydrate. The pKa' values of the new compounds have been determined by potentiometric titration. These and the observed spectroscopic data are discussed and compared with related compounds. A crystalline 1:1 complex of the diamino crown 3b with NaSCN has also been prepared and characterized.