Synthesis, crystal structure and electrochemical behaviour of [2,6-bis(3,5-dimethylpyrazolyl)pyridine](dithiocyanato)cobalt(II)

Arici C., Ulku D., Kurtaran R., EMREGÜL K. C., Atakol O.

Zeitschrift fur Kristallographie, cilt.218, sa.7, ss.497-500, 2003 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 218 Sayı: 7
  • Basım Tarihi: 2003
  • Doi Numarası: 10.1524/zkri.218.7.497.20707
  • Dergi Adı: Zeitschrift fur Kristallographie
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.497-500
  • Ankara Üniversitesi Adresli: Evet

Özet

A mononuclear cobalt(II) complex, [Co(dmpp)(SCN)2], was synthesized using 2,6-bis (3,5-dimethylpyrazolyl)pyridine (dmpp) and thiocyanate anion (SCN), and characterized by IR spectroscopy and single-crystal X-ray diffraction. In addition, cyclic voltammetric studies have been performed. The complex crystalizes in monoclinic space group C 2/c, with unit cell dimensions a = 15.2469(15), b = 9.1120(9), c = 14.0302(11) Å, β = 95.823(3)°. The cell containes 4 molecules.