Nonlinear optical properties of bis[(p-bromophenyl-salicylaldiminato)chloro]iron(III) and its ligand N-(4-bromo)-salicylaldimine

Elmali A., Karakas A., Unver H.

CHEMICAL PHYSICS, cilt.309, sa.2-3, ss.251-257, 2005 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 309 Sayı: 2-3
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1016/j.chemphys.2004.09.013
  • Dergi Adı: CHEMICAL PHYSICS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.251-257
  • Anahtar Kelimeler: nonlinear optical properties, electric dipole moment, first hyperpolarizability, ab initio calculation, SCHIFF-BASE COMPLEXES, ORGANOMETALLIC COMPLEXES, COORDINATION CHEMISTRY, METAL COMPLEXES, DERIVATIVES, CRYSTALS, CHAIN, HYPERPOLARIZABILITY, SALICYLALDEHYDE
  • Ankara Üniversitesi Adresli: Hayır

Özet

A new Schiff base metal complex bis[(p-bromophenyl-salicylaldiminato)chloro]iron(III) [Cl(C(13)H(9)NOBr)(2)Fe] and its ligand (N-(4-bromo)-salicylaldimine) have been synthesized. The title complex and its ligand have been characterized by elemental analysis, IR technique, and UV-Vis spectroscopy. It is found that the investigated compounds have solvatochromic behavior, implying rather well molecular first hyperpolarizability. The ab initio molecular orbital calculations (FF MP2) of the synthesized compounds have been carried out to compute the electric dipole moment (D) and the first hyperpolarizability (beta) values. (C) 2004 Elsevier B.V. All rights reserved.