Electrochemical synthesis of poly(6,7-diphenyl-4,9-di(selenophen-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline-co-3,3-didecyl-3,4-propylenedioxythiophene) and its electrochemical and optical characterizations

Smail S. K., Gokce G., Ozkut M.

POLYMER BULLETIN, cilt.81, sa.16, ss.14499-14511, 2024 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 81 Sayı: 16
  • Basım Tarihi: 2024
  • Doi Numarası: 10.1007/s00289-024-05393-9
  • Dergi Adı: POLYMER BULLETIN
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Sayfa Sayıları: ss.14499-14511
  • Anahtar Kelimeler: 3,4-propylenedioxythiophene, Conjugated copolymer, D-A-D monomer, Low band gap, Quinoline, Selenophene, Soluble polymer, Thiadiazoloquinoxaline
  • Ankara Üniversitesi Adresli: Evet

Özet

In this study, electrochemical copolymerization of 6,7-diphenyl-4,9-di(selenophen-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline and 3,3'-didecyl-3,4-propylenedioxythiophene is carried out to obtain a copolymer namely poly(6,7-diphenyl-4,9-di(selenophen-2-yl)-[1,2,5]thiadiazolo[3,4-g]quinoxaline-co-3,3'-didecyl-3,4-propylenedioxythiophene). Two distinct copolymers, PC1 and PC2, were produced as a result of the utilization of two different feed ratios. Copolymers were examined electrochemically and spectroelectrochemically after the copolymerization procedure. This study's major goal is to combine the exceptional characteristics of homopolymers P1 and P2 (P1 has a low band gap but is not soluble, and P2 is soluble and has a larger band gap) into a single copolymeric material.