Synthesis, Molecular Structure, Biological Activity, and Sensor Properties of (E)-2-[(3,5-Bis(trifluoromethyl)phenylimino)methy1]-4,6-dichlorophenol
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, cilt.91, sa.2, ss.279-284, 2021 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 91 Sayı: 2
- Basım Tarihi: 2021
- Doi Numarası: 10.1134/s107036322102016x
- Dergi Adı: RUSSIAN JOURNAL OF GENERAL CHEMISTRY
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Index Chemicus (IC)
- Sayfa Sayıları: ss.279-284
- Anahtar Kelimeler: single crystal, DFT, DNA interactions, antioxidant, sensor applications
- Ankara Üniversitesi Adresli: Evet
Özet
In the present study, a Schiff base (E)-24(3,5-bis(trifluoromethyl)phenylimino)methyl]-4,6-dichlorophenol has been synthesized. Its spectroscopic and X-ray single -crystal data have been compared with the results of theoretical calculations based on the DFT method, as well as molecular electrostatic potential (MEP), HOMO and LUMO, and nonlinear optical (NLO) effects Antimicrobial activity of the compound has been tested against some bacteria and fungi. According to UV-Vis and agarose gel electrophoresis methods, the compound interacts with DNA electrostatically and breaks it oxidatively. Antioxidant activity of the compound measured by the DPPH method, is lower than that of BHT.