Cosolvent-promoted electrophilic amination of organozinc reagents

DAŞKAPAN T., Yeşilbaǧ F., KOCA S.

Applied Organometallic Chemistry, vol.23, no.6, pp.213-218, 2009 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 23 Issue: 6
  • Publication Date: 2009
  • Doi Number: 10.1002/aoc.1498
  • Journal Name: Applied Organometallic Chemistry
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.213-218
  • Keywords: Aminating agent, Amines, Cosolvent, Electrophilic amination, Organozinc reagents
  • Ankara University Affiliated: Yes

Abstract

In this study, we aimed to develop a simple and efficient method for the electrophilic amination of organozinc reagents. For this reason, 12 cosolvents were screened in the electrophilic amination of ordinary organozinc reagents. By the use of a cosolvent, an easily applicable and high-yielding method for the preparation of arylamines by electrophilic amination of arylzinc reagents was developed. © 2009 John Wiley & Sons, Ltd.