Cosolvent-promoted electrophilic amination of organozinc reagents
Applied Organometallic Chemistry, cilt.23, sa.6, ss.213-218, 2009 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 23 Sayı: 6
- Basım Tarihi: 2009
- Doi Numarası: 10.1002/aoc.1498
- Dergi Adı: Applied Organometallic Chemistry
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.213-218
- Anahtar Kelimeler: Aminating agent, Amines, Cosolvent, Electrophilic amination, Organozinc reagents
- Ankara Üniversitesi Adresli: Evet
Özet
In this study, we aimed to develop a simple and efficient method for the electrophilic amination of organozinc reagents. For this reason, 12 cosolvents were screened in the electrophilic amination of ordinary organozinc reagents. By the use of a cosolvent, an easily applicable and high-yielding method for the preparation of arylamines by electrophilic amination of arylzinc reagents was developed. © 2009 John Wiley & Sons, Ltd.