Cosolvent-promoted electrophilic amination of organozinc reagents

DAŞKAPAN T., Yeşilbaǧ F., KOCA S.

Applied Organometallic Chemistry, cilt.23, sa.6, ss.213-218, 2009 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 23 Sayı: 6
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1002/aoc.1498
  • Dergi Adı: Applied Organometallic Chemistry
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.213-218
  • Anahtar Kelimeler: Aminating agent, Amines, Cosolvent, Electrophilic amination, Organozinc reagents
  • Ankara Üniversitesi Adresli: Evet

Özet

In this study, we aimed to develop a simple and efficient method for the electrophilic amination of organozinc reagents. For this reason, 12 cosolvents were screened in the electrophilic amination of ordinary organozinc reagents. By the use of a cosolvent, an easily applicable and high-yielding method for the preparation of arylamines by electrophilic amination of arylzinc reagents was developed. © 2009 John Wiley & Sons, Ltd.