Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid

DEMİR, AYHAN; Camkerten, Nurettin; Akgun, Hulya; TANYELİ, CİHANGİR; Mahasneh, Ali; Watt, David

doi:10.1080/00397919008053170

Oxidation of aryl alkyl ketones to α-acyloxy, α-(camphorsulfonyloxy), or α-hydroxy derivatives using manganese(iii) acetate in combination with carboxylic acids or (1s)-(+)-10-camphorsulfonic acid

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DEMİR A. G., Camkerten N., Akgun H., TANYELİ C., Mahasneh A. S., Watt D. S.

Synthetic Communications, vol.20, no.15, pp.2279-2289, 1990 (SCI-Expanded)

Publication Type: Article / Article
Volume: 20 Issue: 15
Publication Date: 1990
Doi Number: 10.1080/00397919008053170
Journal Name: Synthetic Communications
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.2279-2289
Ankara University Affiliated: No

Abstract

The a-oxidation of aryl alkyl ketones using manganese(III) acetate in the presence of various carboxylic acids and (1S)-(+)-10-camphorsulfonic acid provided a convenient synthesis of α-acyloxy, a-(10-camphorsulfonyloxy), and a-hydroxy derivatives in good yield. © 1990, Taylor & Francis Group, LLC. All rights reserved.