PHYSICAL REVIEW LETTERS, cilt.94, sa.7, 2005 (SCI-Expanded)
The ferromagnetic interstitial iron compound Fe3C (cementite) is expected to have Invar properties, whereby a high-moment to low-moment transition should occur when the atomic volume is reduced below a critical value. We, therefore, examine the pressure dependence of the Fe K-edge x-ray magnetic circular dichroism in Fe3C at ambient temperature and pressures up to 20 GPa. We find clear evidence for a high-moment to low-moment transition around 10 GPa.