4,4,6,6-Tetrachloro-2,2-(propylene dioxydi-o-phenylenediimino)- 2λ5,4λ5,6λ5- cyclotriphosphazene

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Atıf İçin Kopyala

Tercan B., Hokelek T., Bilge S., Ozguc Z., Kilic Z.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.60, sa.6, 2004 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 60 Sayı: 6
• Basım Tarihi: 2004
• Doi Numarası: 10.1107/s0108270104006894
• Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Ankara Üniversitesi Adresli: Evet

Özet

The title compound, C15H16Cl4N 5O2P3, is a cyclophosphazenic lariat (PNP-pivot) ether with a spiro-cyclic 12-membered macrocyclic ligand containing two ether O and two N atoms; the phosphazene ring is nearly planar. In the macrocyclic ring, there is a four-center (trifurcate) N - H⋯ O/N-H⋯ N hy drogen bond. The relative inner-hole size of the macrocycle is estimated as approximately 0.95 Å.