CATALYST ACTIVITY IN THE COPPER(I) CATALYZED GRIGNARD COUPLING WITH ALKYL-HALIDES CONTAINING BETA-OXYGEN AND GAMMA-OXYGEN FUNCTIONALITY

ERDIK, E; DUSMEZKALENDER, FATMA; OZLU, Y

doi:10.1080/15533179308016657

CATALYST ACTIVITY IN THE COPPER(I) CATALYZED GRIGNARD COUPLING WITH ALKYL-HALIDES CONTAINING BETA-OXYGEN AND GAMMA-OXYGEN FUNCTIONALITY

ERDIK E., DUSMEZKALENDER F., OZLU Y.

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, sa.4, ss.551-558, 1993 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Basım Tarihi: 1993
Doi Numarası: 10.1080/15533179308016657
Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED)
Sayfa Sayıları: ss.551-558
Ankara Üniversitesi Adresli: Evet

Özet

Catalyst activity of several Cu(I) catalysts in the coupling of n-butylmagnesium chloride with alkyl halides containing beta- and gamma-oxygen functionality, free or blocked as acetate and tosylate, has been studied. A marked dependence of the catalyst activity on the heteroatom functionality of the organic halide was found.