The Influence of Solvents on Formation of the Molecular Geometry of [{Fe(salphen)}2O]

KABAK M., ELMALI A.

Turkish Journal of Physics, cilt.22, sa.8, ss.797-801, 1998 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 22 Sayı: 8
  • Basım Tarihi: 1998
  • Dergi Adı: Turkish Journal of Physics
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Sayfa Sayıları: ss.797-801
  • Ankara Üniversitesi Adresli: Evet

Özet

The crystal structure and magnetic properties of the complex (I) = [{Fe(salphen)}2-O]·(C4H8SO) and (II) = [{Fe(salphen)}2O]·(C4H8O2) (salphen H2=N,N′-o-phenylenebis-(salicylidene-imine)) were recently reported [1, 2]. This complex crystallized with the solvents of dimethyl sulfoxide and dioxane. In this paper, we investigate the influence of the solvents on the formation of the molecular geometry and study the orbital mechanism of the magnetic super-exchange interactions of this complex.