Boosting the Efficiency of Perovskite Solar Cells with CsBr-Modified Mesoporous TiO2 Beads as Electron-Selective Contact

Seo J., Uchida R., Kim H., Saygili Y., Luo J., Moore C., ...Daha Fazla

ADVANCED FUNCTIONAL MATERIALS, cilt.28, sa.15, 2018 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 28 Sayı: 15
  • Basım Tarihi: 2018
  • Doi Numarası: 10.1002/adfm.201705763
  • Dergi Adı: ADVANCED FUNCTIONAL MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Anahtar Kelimeler: cesium doping, hysteresis, mesoporous TiO2, passivation, perovskite solar cells, photovoltaics, SURFACE, PHOTOANODE, POLARONS
  • Ankara Üniversitesi Adresli: Hayır

Özet

Rapid extraction of photogenerated charge carriers is essential to achieve high efficiencies with perovskite solar cells (PSCs). Here, a new mesoscopic architecture as electron-selective contact for PSCs featuring 40 nm sized TiO2 beads endowed with mesopores of a few nanometer diameters is introduced. The bimodal pore distribution inherent to these films produces a very large contact area of 200 m(2) g(-1) whose access by the perovskite light absorber is facilitated by the interstitial voids between the particles. Modification of the TiO2 surface by CsBr further strengthens its interaction with the perovskite. As a result, photogenerated electrons are extracted rapidly producing a very high fill factor of close to 80% a V-OC of 1.14 V and a PCE up to 21% with negligible hysteresis.