Dichlorido-1 kappa Cl,3 kappa Cl-bis{mu-2,2 '-[propane1,3-diylbis(iminomethylene)]diphenolato}1 : 2 kappa O-6,N,N ',O ': 2 : 3 kappa O-6,O ': N,N ',O '-tricopper(II)

Ates, Buerke; ERCAN, FİLİZ; Svoboda, Ingrid; Fuess, Hartmut; ATAKOL, ORHAN

doi:10.1107/s1600536808003048

Dichlorido-1 kappa Cl,3 kappa Cl-bis{mu-2,2 '-[propane1,3-diylbis(iminomethylene)]diphenolato}1 : 2 kappa O-6,N,N ',O ': 2 : 3 kappa O-6,O ': N,N ',O '-tricopper(II)

Atıf İçin Kopyala

Ates B. M., ERCAN F., Svoboda I., Fuess H., ATAKOL O.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.64, 2008 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 64
Basım Tarihi: 2008
Doi Numarası: 10.1107/s1600536808003048
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Emerging Sources Citation Index (ESCI), Scopus
Ankara Üniversitesi Adresli: Evet

Özet

The title linear trinuclear copper(II) complex, [Cu-3(C17H20N2O2) Cl-2(2)], was obtained from N,N'-bis(2-hydroxybenzyl)1,3-propanediamine and CuCl2. The overall charge of the three Cu2+ ions is balanced by four deprotonated phenol groups and two Cl- ligands. The complex is centrosymmetric with the central Cu2+ occupying a special position ((1) over bar). This Cu2+ ion is coordinated by the four phenolate O atoms in a square-planar fashion. The second Cu2+ occupies a general position in a square-pyramidal fashion. Two phenolate O atoms and two amine N form the basal plane, with Cl- ligands occupying the fifth coordination site.