Vibrational excitation and relaxation processes in insulators initiated by ultrashort, mid-infrared laser pulses


Haglund R., Cramer R., Ermer D., Papantonakis M., Park H., YAVAŞ Ö.

Conference on Laser Applications in Microelectronic and Optoelectronic Manufacturing IV, San-Jose, Kostarika, 25 - 27 Ocak 1999, cilt.3618, ss.90-101 identifier identifier

  • Yayın Türü: Bildiri / Tam Metin Bildiri
  • Cilt numarası: 3618
  • Basıldığı Şehir: San-Jose
  • Basıldığı Ülke: Kostarika
  • Sayfa Sayıları: ss.90-101
  • Anahtar Kelimeler: ablation, infrared, shock waves, vibrational resonance, desorption-ionization processes, surface instability, CALCITE, ABLATION
  • Ankara Üniversitesi Adresli: Evet

Özet

Ultrashort-pulse lasers are increasingly being used for laser-induced surface modification, texturing and marking of insulators. Ultrashort pulses interacting with insulators in the vibrational infrared produce a number of novel effects of pot intial utility in materials processing and analysis applications, including the creation of microbumps, microdimples, generation of hydrodynamic instabilities, and creation of smooth ablation craters. This paper describes recent results in the study of ultrashort-pulse laser interactions with surfaces when the irradiation is in the 2-10 mu m range. The laser source was a tunable, free-electron laser (FEL) with 1-ps micropulses spaced 350 ps apart in a macropulse lasting up to 4 mu s, with an average power of up to 3 W. This unusual pulse structure makes possible novel tests of the effects of resonant vibrational excitation, controlling the ratio of absorption depth to thermal diffusion length, and desorption and ionization by resonant excitation. The mechanisms underlying these effects, including vibrational excitation and relaxation dynamics, as well as their implications for materials-modification strategies, are discussed with reference to recent experimental examples.