{[μ-Bis(salicylidene)-1,3-propanediaminato]-bis(4-methylpyridine) nickel(II)}dichlorozinc(II)

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Atıf İçin Kopyala

Atakol O., Ercan F., Arici C., Fuess H., Svoboda I.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.55, sa.12, ss.2023-2026, 1999 (SCI-Expanded)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 55 Sayı: 12
• Basım Tarihi: 1999
• Doi Numarası: 10.1107/s0108270199010707
• Dergi Adı: Acta Crystallographica Section C: Crystal Structure Communications
• Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
• Sayfa Sayıları: ss.2023-2026
• Ankara Üniversitesi Adresli: Evet

Özet

The title compound, [Ni(C17H16N2O2)(C6H 7N)2-(ZnCl2)], is a heteronuclear dimeric complex. The Ni atom has an irregular octahedral environment involving two O atoms and two N atoms from the bis(salicylidene)-1,3-propanediaminate ligand in the equatorial plane, and two N atoms from the two 4-methylpyridine groups in the apical positions. The Ni - O -Zn, O - Zn - O, Zn - O - Ni and O - Ni - C) angles in the bridged plane are 99.58 (9), 80.59 (8), 100.57 (9) and 79.26 (8)°, respectively. The Ni⋯Zn distance is 3.0896 (9) Å.