{Bis[2-(2-oxido-1-naphthylmethylideneamino)phenyl] disulfide}chloroiron(III)

Elmali, A; Elerman, Y; Svoboda, I

doi:10.1107/s0108270101000038

{Bis[2-(2-oxido-1-naphthylmethylideneamino)phenyl] disulfide}chloroiron(III)

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Elmali A., Elerman Y., Svoboda I.

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.57, pp.375-376, 2001 (SCI-Expanded)

Publication Type: Article / Article
Volume: 57
Publication Date: 2001
Doi Number: 10.1107/s0108270101000038
Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.375-376
Ankara University Affiliated: No

Abstract

The crystal structure of the title compound, {bis[2-(2-oxido-2-naphthylideneamino)phenyl] disulfide-kappa O-5,N,S,N',O'}chloro-iron(III), [FeCl(C34H22N2O2S2)], has been determined. The structure consists of monomeric iron(III) complexes with distorted octahedral coordination. The disulfide functions as a pentadentate ligand and the Fe-III atom is coordinated through two N, two O and one S atom, and one chloride ion. The distance between the second S atom and the Fe-III atom is a non-bonding 3.8473 (14) Angstrom.