Dichlorobis[2-(o-tolyliminiomethyl)-phenolato-O]zinc(II)


Ulku D., Arici C., Tahir M., Atakol O.

Acta Crystallographica Section C: Crystal Structure Communications, cilt.56, sa.11, ss.1298-1299, 2000 (SCI-Expanded) identifier identifier identifier

Özet

In the mononuclear title compound, [ZnCl2(C14H13NO)2], the ZnII ion is located on a twofold axis of the monoclinic space group so that the whole molecule has a twofold symmetry. The ZnII ion has a tetrahedral coordination consisting of two chlorine ions and the O atoms of the ligands. The coordination angles around zinc have values between 102.89 (8) (O-Zn-O) and 115.83 (5)° (Cl-Zn-O). The Zn-O and Zn-Cl bond lengths are 1.977 (2) and 2.2401 (7) Å, respectively. There are intra- and intermolecular hydrogen bonds in the structure. © 2000 International Union of Crystallography.