Novel and versatile protocol for the preparation of functionalized benzocyclotrimers

Dalkilic E., Gueney M., DAŞTAN A., SARAÇOĞLU N., De Lucchi O., Fabris F.

TETRAHEDRON LETTERS, cilt.50, sa.17, ss.1989-1991, 2009 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 50 Sayı: 17
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.tetlet.2009.02.070
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC), Current Chemical Reactions (CCR)
  • Sayfa Sayıları: ss.1989-1991
  • Ankara Üniversitesi Adresli: Hayır

Özet

2 -Bromo-3-(trimethylstannyl)cyclopenta-1,3-diene is the key-intermediate for the synthesis of vic-bromo(trimethylstannyl)bicycloolefins via Diels-Alder reaction with dienophiles. The cycloadducts can be cyclotrimerized by copper(1)2-thiophenecarboxylate (CuTC) to afford functionalized benzocyclotrimers, (C) 2009 Elsevier Ltd. All rights reserved.