{Bis(N,N-dimethylformamide)[μ-N,N′-bis(salicylidene)-1,3- propane-diaminato]nickel(II)}dibromozinc(II)


Arici C., Svoboda I., Sari M., Atakol O., Fuess H.

Acta Crystallographica, Section C: Crystal Structure Communications, cilt.57, sa.1, ss.31-32, 2001 (SCI-Expanded) identifier identifier identifier

Özet

The title compound, [NiZnBr2(C3H7NO)2(C17H16N2O2)], is a heterodinuclear nickel complex. The Ni atom has an irregular octahedral environment involving two O and two N atoms from the bis(salicylidene)-1,3-propanediaminate ligand in the equatorial plane, and two O atoms from the dimethylformamide groups. The Zn-O-Ni, O-Zn-O, Ni-O-Zn and O-Ni-O angles in the bridged plane are 100.1 (2), 79.9 (2), 100.4 (2) and 78.89 (17)°, respectively. The Ni···Zn distance is 3.0738 (19) angstroms.