Synthesis, spectral properties and structure of new novel 3,3'-dibenzoyl-1,1'-(propan-1,3-diyl)-bisthiourea

AYDIN F., Aykaç D., ÜNVER H., Iskeleli N. O.

Journal of Chemical Crystallography, vol.42, no.4, pp.381-387, 2012 (SCI-Expanded, Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 42 Issue: 4
  • Publication Date: 2012
  • Doi Number: 10.1007/s10870-011-0258-5
  • Journal Name: Journal of Chemical Crystallography
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.381-387
  • Keywords: Bisthiourea, Crystal structure determination, FT-IR, Spectroscopic studies
  • Ankara University Affiliated: Yes

Abstract

A new 3,3'-dibenzoyl-1,1'-propan-1,3-diyl)bisthiourea was synthesized by using benzoylisothiocyanate with 1,3-diaminopropane in aprotic solvent. The structure was determinated by means of FT-IR, 1H-NMR, 13C-NMR and mass spectroscopic techniques. The crystal structure of 3,3'-dibenzoyl-1,1'-(propan-1,3-diyl)bisthiourea has also been examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P2 1/c with the unit cell parameters: a = 5.968(1) Å, b = 19.471(2) Å, c = 16.585(2) Å, β = 98.32(1)°, V = 1907.0 (4) Å 3, Dx = 1.395 g cm -3, and Z = 4 respectively. © Springer Science+Business Media, LLC 2012.