STRUCTURE OF BIS[CHLORO(1-[(4-CHLORO-2-HYDROXYPHENYL)IMINOMETHYL]NAPHTHALEN-2-OLATO-O,O',N)IRON(III)]
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, vol.49, pp.965-967, 1993 (SCI-Expanded)
- Publication Type: Article / Article
- Volume: 49
- Publication Date: 1993
- Doi Number: 10.1107/s0108270192012228
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Academic Search Premier, Aerospace Database, Communication Abstracts, Metadex, Civil Engineering Abstracts
- Page Numbers: pp.965-967
- Ankara University Affiliated: No
Abstract
Two identical [FeLCl] [L = N-(4-chloro-2-hydroxyphenyl)-3-hydroxy-2-naphthaldimine] fragments, related by an inversion centre, are combined by the two bridging O atoms, forming a binuclear unit, dichlorobis-mu-{1-[4-chloro-(2-oxido-1:2kappa2O')-phenyliminomethyl]naphalen 2-olato}-1kappa2N,O;2kappa2N,O-diiron(III). The two iron(III) centres are 3.186 (4) angstrom apart and the distance between the two bridging O atoms amounts to 2.417 (8) angstrom. The two Fe-O distances [Fe-O(2) and Fe-O(2A)] are different [2.047 (8) and 1.951 (8) angstrom, respectively]. The Fe-O(2)-Fe(A) angle in the central four-membered ring is 105.64 (4)degrees.