Preparation of primary arylamines via arylzinc chlorides in good yields

Daskapan T.

TETRAHEDRON LETTERS, cilt.47, sa.17, ss.2879-2881, 2006 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 47 Sayı: 17
  • Basım Tarihi: 2006
  • Doi Numarası: 10.1016/j.tetlet.2006.02.129
  • Dergi Adı: TETRAHEDRON LETTERS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.2879-2881
  • Anahtar Kelimeler: electrophilic amination, organozinc reagents, oxime, arylamines, CATALYZED ELECTROPHILIC AMINATION, NITROGEN, AMINES
  • Ankara Üniversitesi Adresli: Evet

Özet

Primary arylamines can be prepared easily by electrophilic amination of arylzinc chlorides with acetone 0-(2,4,6-tri-methylphenylsulfonyl)oxime in the presence of DMPU as additive and CuCN as catalyst in good yields. (c) 2006 Elsevier Ltd. All rights reserved.