Surface characterization of dinitrophenyl-diaminophenyl nanoplatform on glassy carbon

Eksi H., Gupta V. K., ÜSTÜNDAĞ Z., Atar N., Caglayan M. O., Solak A. O.

JOURNAL OF MOLECULAR LIQUIDS, vol.187, pp.49-53, 2013 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 187
  • Publication Date: 2013
  • Doi Number: 10.1016/j.molliq.2013.05.016
  • Journal Name: JOURNAL OF MOLECULAR LIQUIDS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.49-53
  • Keywords: 2,4-dinitrophenol, ATR-FT-IR, Nanofilm, Ellipsometry, Surface modification, VOLTAMMETRIC SENSOR, IMPEDANCE SPECTROSCOPY, RAMAN-SPECTROSCOPY, URIC-ACID, ELECTRODE, REDUCTION, FABRICATION, MEMBRANE, DNA, GOLD
  • Ankara University Affiliated: Yes

Abstract

2,4-dinitrophenol (DNP) was covalently bonded to glassy carbon substrate by cyclic voltammetry (CV) technique. 2, 4-diaminophenol film (DAPO) was acquired with electrochemical reduction of 2,4-dinitrophenol film (DNPO). Prepared films were characterized by X-ray photoelectron spectroscopy (XPS) and germanium attenuated total reflection infrared (GATR-FT-IR) spectroscopy. A hemispherical germanium ATR element used with p-polarized light at 65 incidence angle yielded high signal/noise IR spectra for monolayer coverage of molecules on glassy carbon substrate. Layer thickness of films was measured using ellipsometer. Nitro and amine groups involved surface were commented on mono-multi layer film thickness with modified cyclic number effects. (C) 2013 Elsevier B.V. All rights reserved.