Crystal structure analysis of {[mu-N,N '-bis(salicylidene)-2,2 '-dimethyl-1,3-propanediaminato](dimethylformamide) zinc(II)}diiodomercury(II)

Arici, C; Ulku, D; Atakol, O; Aksu, M

Crystal structure analysis of {[mu-N,N '-bis(salicylidene)-2,2 '-dimethyl-1,3-propanediaminato](dimethylformamide) zinc(II)}diiodomercury(II)

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Arici C., Ulku D., Atakol O., Aksu M.

CRYSTAL RESEARCH AND TECHNOLOGY, vol.37, no.5, pp.520-527, 2002 (SCI-Expanded)

Publication Type: Article / Article
Volume: 37 Issue: 5
Publication Date: 2002
Journal Name: CRYSTAL RESEARCH AND TECHNOLOGY
Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Page Numbers: pp.520-527
Keywords: crystal structure, dinuclear complex, MAGNETIC-PROPERTIES, ZINC-COMPLEXES, COPPER(II), NUCLEARITY, LIGANDS
Ankara University Affiliated: No

Abstract

The title compound, a hetero-dinuclear complex with Zn-II and Hg-II ions, forms crystals which belong to the monoclinic system, space group P2(1)/n, with unit cell dimensions a = 11.2217(12), b = 17.7493 (11), c = 13.9293(13) Angstrom, beta = 94.830(3)degrees, V = 2764.5(4) Angstrom(3). The cell contains four molecules. The Zn...Hg distance is 3.5362(15) Angstrom.