Enhanced performance based on a hybrid cathode backing layer using a biomass derived activated carbon framework for methanol fuel cells

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Balakrishnan P., GÜRTEN İNAL İ. I., Cooksey E., Banford A., AKTAŞ Z., Holmes S. M.

ELECTROCHIMICA ACTA, cilt.251, ss.51-59, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 251
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.electacta.2017.08.068
  • Dergi Adı: ELECTROCHIMICA ACTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.51-59
  • Anahtar Kelimeler: Direct methanol fuel cells, Microporous layer, Carbon, Activated carbon, Improved power density, GAS-DIFFUSION LAYER, ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY, MICRO-POROUS LAYER, ELECTRODES, CATALYST, BLACK, SIZE
  • Ankara Üniversitesi Adresli: Evet

Özet

Direct methanol fuel cells (DMFCs) suffer from performance reduction due to mass transport losses incurred at high current regions. In this work, we report the use of activated carbon (AC), prepared from factory waste-tea, as cathode microporous layer in the membrane electrode assembly (MEA) of a DMFC, alleviating this mass transport effect. This biomass based AC framework, when tested under fuel cell operating conditions provided 0.25 V @ 300 mA cm (2), enhancing cell performance by 33% over standard electrodes at 70 degrees C. During uninterrupted durability testing, this electrode displayed exceptional stability in mass transport dominated region, with loss of 15 mV day (1), compared to 25 mV day (1) loss for the standard. Sample and electrode characterization measurements reveal that pore size distribution/particle size characteristics coupled with hydrophobic nature of the synthesized activated carbon, contributed to the performance improvement. (C) 2017 Elsevier Ltd. All rights reserved.