Analysis of the Nano-Surface of a Modified Glassy Carbon Electrode by Pseudo Phase Plane Method

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Tenreiro Machado J. A., BALEANU D., DİNÇ E., Solak A. O., Eksi H., GÜZEL R.

JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE, cilt.8, sa.10, ss.1986-1992, 2011 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 8 Sayı: 10
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1166/jctn.2011.1914
  • Dergi Adı: JOURNAL OF COMPUTATIONAL AND THEORETICAL NANOSCIENCE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1986-1992
  • Anahtar Kelimeler: Nano-Film, Modified Glassy Carbon Electrode, Nanoanalysis, Pseudo Phase Plane Method, Mutual Information, Correlation, REDUCTION
  • Ankara Üniversitesi Adresli: Evet

Özet

This paper presents the Pseudo phase plane (PPP) method for detecting the existence of a nanofilm on the nitroazobenzene-modified glassy carbon electrode (NAB-GC) system. This modified electrode systems and nitroazobenze-nanofilnn were prepared by the electrochemical reduction of diazonium salt of NAB at the glassy carbon electrodes (GCE) in nonaqueous media. The IR spectra of the bare glassy carbon electrodes (GCE), the NAB-GC electrode system and the organic NAB film were recorded. The IR data of the bare GC, NAB-GC and NAB film were categorized into five series consisting of FILM1, GC-NAB1, GC1; FILM2, GC-NAB2, GC2; FILM3, GC-NAB3, GC3 and FILM4, GC-NAB4, GC4 respectively. The PPP approach was applied to each group of the data of unmodified and modified electrode systems with nanofilm. The results provided by PPP method show the existence of the NAB film on the modified GC electrode.