An amplified voltammetric sensor based on platinum nanoparticle/polyoxometalate/two-dimensional hexagonal boron nitride nanosheets composite and ionic liquid for determination of N-hydroxysuccinimide in water samples

Karimi-Maleh, Hassan; Karimi, Fatemeh; Malekmohammadi, Samira; Zakariae, Nilofar; Esmaeili, Roghayeh; Rostamnia, Sadegh; Yola, MEHMET; Atar, Necip; Movaghgharnezhad, Shirin; Rajendran, Saravanan; Razmjou, Amir; Orooji, Yasin; Agarwal, Shilpi; Gupta, Vinod

doi:10.1016/j.molliq.2020.113185

An amplified voltammetric sensor based on platinum nanoparticle/polyoxometalate/two-dimensional hexagonal boron nitride nanosheets composite and ionic liquid for determination of N-hydroxysuccinimide in water samples

Karimi-Maleh H., Karimi F., Malekmohammadi S., Zakariae N., Esmaeili R., Rostamnia S., ...Daha Fazla

JOURNAL OF MOLECULAR LIQUIDS, cilt.310, 2020 (SCI-Expanded, Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 310
Basım Tarihi: 2020
Doi Numarası: 10.1016/j.molliq.2020.113185
Dergi Adı: JOURNAL OF MOLECULAR LIQUIDS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Chimica, Compendex, INSPEC
Ankara Üniversitesi Adresli: Hayır

Özet

In this study, a novel electrochemical method as a conductive voltammetric sensor for determination of N-hydroxysuccinimide was developed. The N-hydroxysuccinimide sensor was achieved by carbon paste electrode (CPE) amplified with tri-component nanohybrid composite (Platinum nanoparticle/Polyoxometalate/ Two-dimensional hexagonal boron nitride nanosheets) (PtNPs/POM/2D-hBN) and 1-hexyl-3-methylimidazolium chloride (HMICl) as conductive mediators. A significant decrease (110 mV) in the oxidation overvoltage and significant increased (2.4 times) in the current of the N-hydroxysuccinimide were observed using HMICl-PtNPs/POM/2D-hBN/POMBNS/CPE. Furthermore, the HMICl-PtNPs/POM/2D-hBN/POMBNS/CPE exhibited a good linearity from 0.1 to 300 mu M and detection limit 60 nM for determination of N-hydroxysuccinimide. The capability to promote the electron exchange between N-hydroxysuccinimide and the HMICl-PtNPs/POM/2D-hBN/POMBNS/CPE exhibited a novel analytical strategy for fabrication of water pollutant sensor. (C) 2020 Elsevier B.V. All rights reserved.